Olivier Schneider in 'Unknown'
Olivier Schneider
Unknown (2011) [Smith]: Stabbed in the neck with his own syringe and injected with poison by Diane Kruger while Olivier is trying to kill Liam Neeson. (Thanks to ND)

(Note: As a professional stunt performer, Olivier has probably "died" in place of other actors, though I don't know any specific examples.)
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